Rajeev Chaubey
Tuesday, December 31, 2013
Thursday, December 12, 2013
Fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore lower energy, than the absorbed radiation. However, when the absorbed electromagnetic radiation is intense, it is possible for one electron to absorb two photons; this two-photon absorption can lead to emission of radiation having a shorter wavelength than the absorbed radiation. The emitted radiation may also be of the same wavelength as the absorbed radiation, termed "resonance fluorescence"
Photoluminescence
Photoluminescence (abbreviated as PL) describes the phenomenon of light emission from any form of matter after the absorption of photons (electromagnetic radiation). It is one of many forms of luminescence (light emission) and is initiated by photoexcitation (excitation by photons), hence the prefix photo-. The excitation typically undergoes various relaxation processes and then photons are re-radiated. The period between absorption and emission can be extremely short: it ranges from the femtosecond-regime for the emission from, e.g., free-carrier plasma in inorganic semiconductors up to milliseconds for phosphorescent processes in molecular systems; however, it can also be extended into minutes or hours under special circumstances.
A strong photoluminescence enhancement effect of illumination on CdTe nanocrystals stabilized by thioglycolic acid (TGA) was observed. Under optimized conditions, the fluorescence quantum yield of CdTe nanocrystals in aqueous solution reached 85% at room temperature. Optical measurements indicated that the photodegradation of TGA rather than NCs was the main reason for the PL enhancement effect since sulfide ions released from TGA during illumination coordinated with cadmium ions on the surface of CdTe and formed a shell structure of CdS there. X-ray photoelectron spectroscopic results further proved the formation of CdS shell on the CdTe core during illumination. The colloidal solution of CdTe/CdS core−shell nanocrystals with photoluminescence quantum yield higher than 80% turned out to be very stable. Therefore, the current investigations not only reveal the PL enhancement effect of illumination, but also provide a useful synthetic route for producing water-soluble and highly fluorescent CdTe/CdS core−shell nanocrystals.
A strong photoluminescence enhancement effect of illumination on CdTe nanocrystals stabilized by thioglycolic acid (TGA) was observed. Under optimized conditions, the fluorescence quantum yield of CdTe nanocrystals in aqueous solution reached 85% at room temperature. Optical measurements indicated that the photodegradation of TGA rather than NCs was the main reason for the PL enhancement effect since sulfide ions released from TGA during illumination coordinated with cadmium ions on the surface of CdTe and formed a shell structure of CdS there. X-ray photoelectron spectroscopic results further proved the formation of CdS shell on the CdTe core during illumination. The colloidal solution of CdTe/CdS core−shell nanocrystals with photoluminescence quantum yield higher than 80% turned out to be very stable. Therefore, the current investigations not only reveal the PL enhancement effect of illumination, but also provide a useful synthetic route for producing water-soluble and highly fluorescent CdTe/CdS core−shell nanocrystals.
Luminescence
Luminescence is "cold light" that can be emitted at normal and lower temperatures. In luminescence, some energy source kicks an electron of an atom out of its lowest energy "ground" state into a higher energy "excited" state; then the electron returns the energy in the form of light so it can fall back to its "ground" state. With few exceptions, the excitation energy is always greater than the energy (wavelength, color) of the emitted light.
Monday, December 9, 2013
Friday, December 6, 2013
Project
Currently I am working in th project of META MATERIAL.
This is type of artificial material used for hiding the particles.
For more details. www.opticalcomm.blogspot.com
www.opticalimaging.blogspot.com
This is type of artificial material used for hiding the particles.
For more details. www.opticalcomm.blogspot.com
www.opticalimaging.blogspot.com
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